Sources of dissolved organic carbon during stormflow in a headwater agricultural catchment     

B. Morel  P. Durand  A. Jaffrezic  G. Gruau  J. Molenat 《水文研究》2009,23(20):2888-2901

Increasing dissolved organic carbon (DOC) concentrations have been reported during the last 15 years in streams from the United Kingdom, Northern Europe and North America. Identifying the sources of DOC and the controls of the delivery to the stream is important to understand the significance of these trends. This relies on the availability of observations of DOC dynamics during storm events, since much of the DOC export from soils to streams occurs during high flows. This study analyses DOC data for eight storm events during winter 2005–2006 in a small agricultural experimental catchment—the Kervidy‐Naizin experimental catchment—located in Western France. A four end‐member mixing approach was applied to the eight monitored storm events to identify DOC sources and quantify their respective contribution to DOC stream fluxes, using DOC, nitrate, sulphate and chloride as tracers. The results show that DOC concentrations in the stream at the outlet of this catchment increase markedly during storm events. The slope of the linear regression between DOC concentration and discharge was not constant for the eight events and depended on pre‐event hydrological conditions. Between 64 and 86% of the DOC that enter the stream during storms originated from the upper layers of the riparian wetland soils. The variation of the delivery of DOC seems to be controlled by hydrological processes only, the wetland soils acting as a non‐limiting store. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Meteoroid Bulk Density Determination Using Radar Head Echo Observations     

K. Drew  P. G. Brown  S. Close  D. Durand 《Earth, Moon, and Planets》2004,95(1-4):639-645

We present the results of a study of meteoroid bulk densities determined from meteor head echoes observed by radar. Meteor observations were made using the Advanced Research Projects Agency Long-Range Tracking And Instrumentation Radar (ALTAIR). ALTAIR is particularly well suited to the detection of meteor head echoes, being capable of detecting upwards of 1000 meteor head echoes per hour. Data were collected for 19 beam pointings and are comprised of approximately 70 min. of VHF observations. During these observations the ALTAIR beam was directed largely at the north apex sporadic source. Densities are calculated using the classical physical theory of meteors. Meteoroid masses are determined by applying a full wave scattering theory to the observed radar cross-section. Observed meteoroids are predominantly in the 10⁻¹⁰ to 10⁻⁶ kg mass range. We find that the vast majority of meteoroid densities are consistent with low density, highly porous objects as would be expected from cometary sources. The median calculated bulk density was found to be 900 kg/m³. The orbital distribution of this population of meteoroids was found to be highly inclined.  相似文献   

New insight into the structure of nanocrystalline ferrihydrite: EXAFS evidence for tetrahedrally coordinated iron(III)   总被引：1，自引：0，他引：1  

Fabien Maillot  Yuheng Wang  Philippe Ildefonse  Corinne Chaneac 《Geochimica et cosmochimica acta》2011,75(10):2708-9890

Ferrihydrite (Fh) is a short-range ordered nanocrystalline iron(III) (oxyhydr)oxide that has been recognized to play an important role in contaminant sequestration and in iron cycling in geological and biological systems. Despite intensive research for the two last decades, the structure of Fh is still a subject of debate. In the present study, we report extended X-ray absorption fine structure (EXAFS) spectroscopy data collected on a large set of ferrihydrites and model compounds samples including especially nano-crystalline maghemite (Mh), goethite (Gt), and akaganeite (Aka). This set of EXAFS data recorded at cryogenic temperature over a wide energy range allows us to precisely determine the Fe-O mean distance (〈Fe-O〉) in the first coordination shell of iron for this large set of iron (oxyhydr)oxides. Our EXAFS analysis includes both classical shell-by-shell fits of Fourier-filtered and unfiltered data as well as analysis of Fe-O distance distribution in the first coordination shell of iron using the Landweber iteration method. 〈Fe-O〉 determined by these complementary EXAFS analyses are similar: 〈Fe-O〉 is shorter in Mh (1.96 ± 0.01 Å) that contains 37.5% of tetrahedral iron, than in Gt (2.01 ± 0.01 Å), Aka (2.00 ± 0.01 Å) and hematite (Hm) (2.01 ± 0.01 Å) that do not contain tetrahedral iron. 〈Fe-O〉 for the five Fh samples investigated (1.97 ± 0.01 Å) was found to be slightly longer than in Mh and significantly shorter than those in Gt, Aka and Hm. This short 〈Fe-O〉 distance in Fh indicates the presence of significant amount of tetrahedrally coordinated iron(III) in all Fh samples studied, which ranges between 20 ± 5% and 30 ± 5% of total iron. In addition, our analysis of Fe-Fe distances observed by EXAFS is consistent with a Keggin-like motif at a local scale (∼5 Å) in the Fh structure.  相似文献   

Criteria for the identification of ventifacts in the geological record: A review and new insights   总被引：1，自引：0，他引：1  

Marc Durand  Sylvie Bourquin 《Comptes Rendus Geoscience》2013,345(3):111-125

Ventifacts (wind-worn stones) are typical of terrestrial environments remained very long without any vegetation, under hot or cold climates. Therefore, within the sedimentary record, they can allow recognizing desert conditions, even where no aeolian dune deposits are preserved. There seems that, in the recent literature, pebbles and cobbles from various palaeoenvironments were mistaken for ventifacts. This may partly be explained by the scatter and relative scarcity of illustrations to which refer. The aim of this paper is to help recognizing ventifacts in the sedimentary record, based on a critical review of the diagnostic properties generally used, and on new studies permitting to suggest additional criteria. After an evaluation of the sedimentary contexts favourable to preserving ventifacts, the distinctive characters that could be seen on each one are treated in order of increasing alteration of the original appearance: surface features, medium-scale features (new types of pit especially), and general shape. Finally, the problem of distinguishing between ventifacts and aquafacts is approached.  相似文献   

Influence of sample location and livestock numbers on Sporormiella concentrations and accumulation rates in surface sediments of Lake Allos, French Alps     

David Etienne  Bruno Wilhelm  Pierre Sabatier  Jean-Louis Reyss  Fabien Arnaud 《Journal of Paleolimnology》2013,49(2):117-127

Spores of coprophilous fungi, especially Sporormiella, are often well preserved in lake sediment cores. It has been hypothesized that such spores can be used to quantify past livestock abundance. The quantitative relationship between fungal spore abundance and livestock populations, however, is not well established, nor are the mechanisms of spore transport and deposition in lacustrine systems. Multiple cores from Lake Allos, a large high-elevation lake in the French Alps, were used to map the modern abundance of Sordaria and Sporormiella spores throughout the lake. We observed high spatial heterogeneity with respect to spore numbers. No correlation with the distance from shoreline was found. There was, however, a relation with distance from the two main lake inlets. These results were used to select two fungi-rich sediment cores to investigate grazing pressure over the last two centuries. Comparisons were made between spore influx and historic data on livestock densities in the catchment. A sharp decrease in Sporormiella influx ca. 1894–1895 was associated with a reported reduction in sheep in the Allos catchment at that time. Mean influx of Sporormiella decreased by a factor of three between the nineteenth and twentieth centuries, reflecting a reduction in the reported number of animals in the Lake Allos catchment, from 6,000 to 2,000. This study confirmed that Sporormiella spore abundance in lake sediments can be used as a proxy for catchment herbivore numbers in paleoecological reconstructions. Nevertheless, our data indicate that before spore accumulation can be used to infer past domestic herbivore density, one must understand the processes of coprophilous spore transfer from the catchment to the lake and the influence of core location on spore numbers in the sediment.  相似文献   

A 70 Ma record of suprasolidus conditions in the large,hot, long‐duration Grenville Orogen          下载免费PDF全文

François Turlin  Clara Deruy  Aurélien Eglinger  Olivier Vanderhaeghe  Anne‐Sylvie André‐Mayer  Marc Poujol  Abdelali Moukhsil  Fabien Solgadi 《地学学报》2018,30(3):233-243

Petrochronology of magmatic monazite and apatite from a single paragneiss leucosome derived by in situ partial melting documents the thermal evolution of the Allochthonous Belt of the central Grenville Province. Monazite records suprasolidus metamorphism from ca. 1080 to 1020 Ma under high temperature up to 850°C. Apatite from the same leucosome yields an age of 960 Ma, consistent with cooling of this crustal segment down to subsolidus conditions of ca. 450°C. A pegmatitic granite dyke, with lobate contacts, previously dated at ca. 1005 Ma (Turlin et al., 2017 ) is interpreted to intrude the paragneisses at a temperature of ca. 650°C close to the wet‐solidus. These data document slow cooling at a rate of 2–6°C/Ma for the middle crust of this part of the Grenville hinterland marked by protracted suprasolidus conditions for at least 70 Ma. It supports the definition of the Grenville Orogen as a large, hot, long‐duration orogen.  相似文献   

Diachronic metamorphic and structural evolution of the Connecticut Valley–Gaspé trough,Northern Appalachians     

Morgann Perrot  Alain Tremblay  Gilles Ruffet  Loic Labrousse  Félix Gervais  Fabien Caroir 《Journal of Metamorphic Geology》2020,38(1):3-27

The Connecticut Valley–Gaspé (CVG) trough represents a major, orogen-scale Silurian–Devonian basin of the Northern Appalachians. From Gaspé Peninsula to southern New England, the CVG trough has experienced a contrasting metamorphic and structural evolution during the Acadian orogeny. Along its strike, the CVG trough is characterized by increasing strain and polyphase structures, and by variations in the intensity of regional metamorphism and contrasting abundance of c. 390–370 Ma granitic intrusions. In southern Quebec and northern Vermont, a series of NW–SE transects across the CVG trough have been studied in order to better understand these along-strike variations. Detailed structural analyses, combined with phase equilibria modelling, Raman spectrometry, and muscovite ⁴⁰Ar/³⁹Ar dating highlight a progressive and incremental deformation involving south–north variation in the timing of metamorphism. Deformation evolves from a D₁ crustal thickening event which originates in Vermont and progresses to southern Québec where it peaked at 0.6 GPa/380°C at c. 375 Ma. This was followed by a D₂ event associated with continuous burial in Vermont from 378 to 355 Ma, which produced peak metamorphic conditions of 0.85 GPa/380°C and exhumation in Quebec from 368 to 360 Ma. The D₃ compressional exhumation event also evolved from south to north from 345 to 335 Ma. D₁ to D₃ deformation events form part of a continuum with an along-strike propagation rate of ~50 km/Ma During D₁, the burial depth varied by more than 15 km between southern Quebec and Vermont, and this can be attributed to the occurrence of a major crustal indenter, the Bronson Hill Arc massif, in the New England segment of the Acadian collision zone.  相似文献   

New insights into the origin and evolution of Lake Vida,McMurdo Dry Valleys,Antarctica — A noble gas study in ice and brines     

Jessica L. Malone  M. Clara Castro  Chris M. Hall  Peter T. Doran  Fabien Kenig  Chris P. McKay 《Earth and Planetary Science Letters》2010,289(1-2):112-122

Unlike other lakes in the McMurdo Dry Valleys, Antarctica, Lake Vida has a thick (~ 19 m) ice cover sealing a liquid brine body of unusually high salinity (~ 245 g/L) from the atmosphere. To constrain the conditions under which the atypical Lake Vida ice cover formed and evolved, 19 ice samples were collected down to a depth of ~ 14 m, together with three brine samples trapped in the ice at ~ 16 m for analysis of helium, neon, argon, krypton, and xenon concentrations. The broad pattern of noble gas concentrations for Lake Vida samples is fundamentally different from that of air saturated water (ASW) at 0 °C and an elevation of 340 m for salinities of 0 (ice) and 245 g/L (brine). Overall, ice samples are enriched in He and depleted in Ne with saturation relative to ASW averages of 1.38 and 0.82, respectively, and strongly depleted in Ar, Kr, and Xe with relative saturations of 0.10, 0.06, and 0.05, respectively. By contrast, brine samples are generally depleted in He and Ne (relative saturation averages of 0.33 and 0.27, respectively) but enriched in Ar, Kr, and Xe, with relative saturation averages of 1.45, 3.15, and 8.86, respectively. A three-phase freezing partitioning model generating brine, ice and bubble concentrations for all stable noble gases was tested and compared with our data. Measured brine values are best reproduced for a salinity value of 175 g/L, a pressure of 1.1 atm, and a bubble volume of 20 cm³ kg^?1. Sensitivity tests for ice + bubble samples show an ideal fit for bubble volumes of ~ 1–2 cm³ kg^?1. Our results show that the conditions under which ice and brine formed and evolved at Lake Vida are significantly different from other ice-covered lakes in the area. Our brine data suggest that Lake Vida may be transitioning from a wet to a dry-based lake, while the ice + bubble data suggest at least partial re-equilibration of residual liquid with the atmosphere as ice forms at the top of Lake Vida ice cover.  相似文献   

Partitioning evapotranspiration fluxes into soil evaporation and plant transpiration using water stable isotopes under controlled conditions   总被引：1，自引：0，他引：1  

Youri Rothfuss  Philippe Biron  Isabelle Braud  Laurent Canale  Jean‐Louis Durand  Jean‐Paul Gaudet  Patricia Richard  Michel Vauclin  Thierry Bariac 《水文研究》2010,24(22):3177-3194

  相似文献   

GPS estimates of ocean tide loading in NW-France: determination of ocean tide loading constituents and comparison with a recent ocean tide model   总被引：3，自引：0，他引：3  

M. Vergnolle  M.-N. Bouin  L. Morel  F. Masson †  S. Durand  J. Nicolas  S. A. Melachroinos 《Geophysical Journal International》2008,173(2):444-458

  相似文献